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Bioinspired Mono- and Dinuclear Nickel, Zinc and Copper Complexes for the Binding and Transformation of Biorelevant Substrates - Couverture souple

 
9783736992511: Bioinspired Mono- and Dinuclear Nickel, Zinc and Copper Complexes for the Binding and Transformation of Biorelevant Substrates
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  • ÉditeurCuvillier Verlag
  • Date d'édition2016
  • ISBN 10 3736992513
  • ISBN 13 9783736992511
  • ReliureBroché
  • Nombre de pages252
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Natascha Bruckner
Edité par Cuvillier Mai 2016 (2016)
ISBN 10 : 3736992513 ISBN 13 : 9783736992511
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BuchWeltWeit Ludwig Meier e.K.
(Bergisch Gladbach, Allemagne)
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Description du livre Taschenbuch. Etat : Neu. This item is printed on demand - it takes 3-4 days longer - Neuware -The synthesis of model systems is of great interest for understanding metalloenzyme active site features, and for developing biomimetic catalysts. Compartmental ligands based on macrocyclic systems and on 3,5-disubstituted pyrazolate bridges are well suited. Especially the latter ones were generated to synthesis highly preorganised bimetallic complexes with tuneable metal¿¿¿metal separations in the range 3.5¿4.5 Å. Appending second sphere functions for H-bonding interactions may enhance, in a biomimetic approach, the activation of bound substrates or the stabilisation of catalytic intermediates. With these ligands, synthetic and functional model complexes based on the proteins urease, phosphotriesterase and hemocyanin should be synthesised and characterised on their binding properties and their abilities to transform biorelevant substrates like urea, phosphoesters and dioxygen. For their characterisation and catalytical properties several analytical methods like UV/vis, IR, NMR and resonance Raman spectroscopy as well as mass spectrometry were used. 252 pp. Englisch. N° de réf. du vendeur 9783736992511

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Natascha Bruckner
Edité par Cuvillier (2016)
ISBN 10 : 3736992513 ISBN 13 : 9783736992511
Neuf Taschenbuch Quantité disponible : 1
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AHA-BUCH GmbH
(Einbeck, Allemagne)
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Description du livre Taschenbuch. Etat : Neu. nach der Bestellung gedruckt Neuware - Printed after ordering - The synthesis of model systems is of great interest for understanding metalloenzyme active site features, and for developing biomimetic catalysts. Compartmental ligands based on macrocyclic systems and on 3,5-disubstituted pyrazolate bridges are well suited. Especially the latter ones were generated to synthesis highly preorganised bimetallic complexes with tuneable metal¿¿¿metal separations in the range 3.5¿4.5 Å. Appending second sphere functions for H-bonding interactions may enhance, in a biomimetic approach, the activation of bound substrates or the stabilisation of catalytic intermediates. With these ligands, synthetic and functional model complexes based on the proteins urease, phosphotriesterase and hemocyanin should be synthesised and characterised on their binding properties and their abilities to transform biorelevant substrates like urea, phosphoesters and dioxygen. For their characterisation and catalytical properties several analytical methods like UV/vis, IR, NMR and resonance Raman spectroscopy as well as mass spectrometry were used. N° de réf. du vendeur 9783736992511

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Bruckner, Natascha
ISBN 10 : 3736992513 ISBN 13 : 9783736992511
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moluna
(Greven, Allemagne)
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Description du livre Etat : New. Dieser Artikel ist ein Print on Demand Artikel und wird nach Ihrer Bestellung fuer Sie gedruckt. KlappentextrnrnThe synthesis of model systems is of great interest for understanding metalloenzyme active site features, and for developing biomimetic catalysts. Compartmental ligands based on macrocyclic systems and on 3,5-disubstituted pyrazol. N° de réf. du vendeur 121798383

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