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Umpoled Synthons: Survey of Sources and Uses in Synthesis (Hardback)

Edité par John Wiley Sons Inc, United States, 1987
ISBN 10: 0471806676 / ISBN 13: 9780471806677
Neuf(s) / Hardback / Quantité : 1
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Titre : Umpoled Synthons: Survey of Sources and Uses...

Éditeur : John Wiley Sons Inc, United States

Date d'édition : 1987

Reliure : Hardback

Etat du livre : New

Description :

Language: English . Brand New Book. The purpose of this book is to provide chemists who plan their synthetic routes manually with information on some of the new umpoled synthons. The introductory chapter examines, in general, the use of synthons in planning organic syntheses. Concluding the introduction is a fairly detailed list of generally convenient synthons that are, however, extraneous to the main contents of the book. A major portion of the book is devoted to acyl anions, hydroxycarbonyl and related anions, carbonyl-cations and carbonyl-anions. A further group comprises carbanionic synthons in which the carbon atom carries a singly bonded heteroatom (O,S,N, or halogen). In appropriate chapters, the above synthons are surveyed with emphasis on the aspects relating to synthetic use. The book concludes with a tabular presentation of known applications of these synthons, with relevant data on the sources, auxiliary reagents, yields and restrictions. N° de réf. du libraire AAH9780471806677

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Synopsis : Since the introduction of the concept of synthons in 1967, it has become common among practitioners of organic synthesis to treat numerous synthetic reactions as simple combinations of the appropriate synthons instead of writing out the actual reagents in full. This book provides chemists who plan their synthetic routes manually with information on some of the new umpoled synthons and the use of synthons in planning organic syntheses. The major part of the text is devoted to acyl anions, hydroxycarbonyl and related anions, carbonyl (ALPHA)?cations, and carbonyl (BETA)?anions. Another group discussed comprises carbanionic synthons in which the carbon atom carries a singly bonded heteratom. Emphasis is on the aspects relating to synthetic use. This work includes a tabular presentation of known applications, along with relevant data on the sources, auxiliary reagents, yields, and restrictions. More than 2,000 references cited.

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