Reaction Mechanisms of Inorganic and Organometallic Systems - Couverture rigide

Jordan, Robert B.

Couverture rigide

ISBN 10 : 0195069455 ISBN 13 : 9780195069457

Editeur : Oxford University Press Inc, 1991

Synopsis

This book is intended as a chemistry text for a one-semester course on inorganic reaction mechanisms at the advanced undergraduate or graduate level. Introductory chapters concentrate on the collection and intrepretation of kinetic data. The chapter on substitution reactions begins with the Langford and Gray classification system and focuses on a sensible approach to mechanistic discussions. Current experimental and theoretical information on solvent exchange reactions is emphasized for substitution on labile systems. Standard stereochemical change processes are discussed, along with a simplified approach to symmetry rules for fluxional organometallic systems. The area of organometallic reactions attempts to bring together and generalize the current work on a variety of common reactions in this area, including C-H activation and a selection of catalytic processes. Electron transfer reactions are discussed in terms of current modifications of Marcus' theory and ideas about bridging ligand effects, including intravalence electron transfer. In inorganic photochemistry, the general factors affecting quantum yields are discussed, with applications to cobalt (III), chromuim (III), and rhodium (III) systems, along with flash photolysis and matrix isolation studies in organometallic photochemistry. Selected bioinorganic systems are discussed in detail. The text includes over 500 references to original literature through 1990, and sample problems for each chapter.

A propos du livre

Présentation de l'éditeur

This third edition retains the general level and scope of earlier editions, but has been substantially updated with over 900 new references covering the literature through 2005, and 140 more pages of text than the previous edition. In addition to the general updating of materials, there is new or greatly expanded coverage of topics such as Curtin-Hammett conditions, pressure effects, metal hydrides and asymmetric hydrogenation catalysts, the inverted electron-transfer region, intervalence electron transfer, photochemistry of metal carbonyls, methyl transferase and nitric oxide synthase. The new chapter on heterogeneous systems introduces the basic background to this industrially important area. The emphasis is on inorganic examples of gas/liquid and gas/liquid/solid systems and methods of determining heterogeneity.

Présentation de l'éditeur

This is a textbook for a one semester course at the advanced undergraduate or graduate level. Two introductory chapters discuss the collection and analysis of kinetic data. Subsequent chapters cover ligand substitution mechanisms, stereochemical change and fluxional processes, electron transfer reactions, inorganic and organometallic photochemistry, selected bioinorganic systems, and experimental methods. There are sample problems for each chapter and over 900 references to the original literature.

Détails de l'édition

• Éditeur: Oxford University Press Inc
• Date d'édition: 1991
• Langue: anglais
• ISBN 10: 0195069455
• ISBN 13: 9780195069457
• Reliure: Relié
• Nombre de pages: 291
• Coordonnées du fabricant: non disponible
• Personne responsable: Buchpark GmbH; gpsr@buchpark.de; ; Krügerweg 1; Trebbin; Brandenburg; 14959; Allemagne