Synopsis
Excerpt from On the Nature of the Crystal Field Approximation
Attempts to calculate the parameters in crystal field theory from electrostatic models have had mixed success. A recent careful calculation by Kleiner11 of the crystal field splitting constant in chrome alum, gave the wrong magnitude and sign., Tanabe and. Sugano12 have carried out calcuiations of the. Crystal fieid parameter on the basis of a molecular orbital treatment of the omplex made up of the reference ion and its nearest neighbors. They find a t parameter of correct sign and magnitude. Their chief improvement over Kleiner''e calculation is the careful treatment of exchange between the electrons on the reference ion and those eh the nearest neighbors.
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On the Nature of the Crystal Field Approximation (Classic Reprint)
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On the Nature of the Crystal Field Approximation (Classic Reprint)
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HRD. Etat : New. New Book. Shipped from UK. Established seller since 2000. N° de réf. du vendeur LW-9780265881477
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