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9783030077921: Free-Radical Synthesis and Functionalization of Heterocycles

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ISBN 10 : 3030077926 ISBN 13 : 9783030077921

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�diteurSpringer
Date d'�dition2019
ISBN 10 3030077926
ISBN 13 9783030077921
ReliureBroch�
Langueanglais
Nombre de pages360
�diteurLandais Yannick

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Free-Radical Synthesis and Functionalization of Heterocycles

Landais, Yannick

Edit� par Springer International Publishing, 2019

ISBN 10 : 3030077926 ISBN 13 : 9783030077921

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Etat : New. Dieser Artikel ist ein Print on Demand Artikel und wird nach Ihrer Bestellung fuer Sie gedruckt. Provides readers with an overview of free-radical chemistry as an environmentally benign synthetic strategy to access heterocyclesEmphasizes the high bond forming efficiency of using radical cascade and electron-transfer processes. N� de r�f. du vendeur 448670955

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Free-Radical Synthesis and Functionalization of Heterocycles

Yannick Landais

Edit� par Springer International Publishing, Springer International Publishing, 2019

ISBN 10 : 3030077926 ISBN 13 : 9783030077921

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Taschenbuch. Etat : Neu. Druck auf Anfrage Neuware - Printed after ordering - This volume describes the recent developments in the free-radical mediated synthesis and elaboration of heterocycles. The first chapter, dealing with radical cascade processes illustrates the power and the beauty of radical chemistry with some striking examples of total synthesis of complex natural heterocycles. As organic chemists strive towards sustainability, radical chemistry has recently seen major advances and efforts in this direction, including C-H activation of arenes and unactivated alkyl groups. Photochemical activation, for a long time the preferred mode of activation in radical chemistry has also seen an unexpected revival with the advent of visible light metal- and organocatalyzed photoredox processes. A survey of these emerging areas is provided along with the concepts at the origin of these developments. The venerable Minisci reaction allows for direct access to functionalized heterocycles. This process has lately seen an interesting renaissance and is discussed in this volume. Addition of heteroatom-centered radicals onto unsaturated systems constitutes another powerful method to construct heterocycles. Examples of such a strategy are proposed along with the formation of various heterocycles relying on homolytic substitution at sulfur, phosphorus and selenium. Additionally free-radical functionalization of reactive functional groups including isonitriles, isothiocyanates and related unsaturated systems which offer a straightforward route towards useful aromatic and non-aromatic heterocycles are discussed. Finally, as metals are able to trigger single electron transfer both in reductive and oxidative modes this provides another possibility for the synthesis of heterocycles. Significant research efforts have focused on the use of samarium, copper and other metals to access a broad variety of heterocycles in a single pot process, starting from readily available raw material. Examples and mechanistic insights are discussed by experts in thisarea. N� de r�f. du vendeur 9783030077921

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Free-Radical Synthesis and Functionalization of Heterocycles

Yannick Landais

Edit� par Springer International Publishing Feb 2019, 2019

ISBN 10 : 3030077926 ISBN 13 : 9783030077921

Neuf Taschenbuch

impression � la demande

Vendeur : BuchWeltWeit Ludwig Meier e.K., Bergisch Gladbach, Allemagne

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Taschenbuch. Etat : Neu. This item is printed on demand - it takes 3-4 days longer - Neuware -This volume describes the recent developments in the free-radical mediated synthesis and elaboration of heterocycles. The first chapter, dealing with radical cascade processes illustrates the power and the beauty of radical chemistry with some striking examples of total synthesis of complex natural heterocycles. As organic chemists strive towards sustainability, radical chemistry has recently seen major advances and efforts in this direction, including C-H activation of arenes and unactivated alkyl groups. Photochemical activation, for a long time the preferred mode of activation in radical chemistry has also seen an unexpected revival with the advent of visible light metal- and organocatalyzed photoredox processes. A survey of these emerging areas is provided along with the concepts at the origin of these developments. The venerable Minisci reaction allows for direct access to functionalized heterocycles. This process has lately seen an interesting renaissance and is discussed in this volume. Addition of heteroatom-centered radicals onto unsaturated systems constitutes another powerful method to construct heterocycles. Examples of such a strategy are proposed along with the formation of various heterocycles relying on homolytic substitution at sulfur, phosphorus and selenium. Additionally free-radical functionalization of reactive functional groups including isonitriles, isothiocyanates and related unsaturated systems which offer a straightforward route towards useful aromatic and non-aromatic heterocycles are discussed. Finally, as metals are able to trigger single electron transfer both in reductive and oxidative modes this provides another possibility for the synthesis of heterocycles. Significant research efforts have focused on the use of samarium, copper and other metals to access a broad variety of heterocycles in a single pot process, starting from readily available raw material. Examples and mechanistic insights are discussed by experts in this area. 360 pp. Englisch. N� de r�f. du vendeur 9783030077921

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