Even some fifty years after their discovery, transition metals have lost none of their fascination. The use of complex compounds in these elements has not only revolutionized synthesis in the laboratory, but has also led to them playing an important role in many industrial applications. Each year, millions of tons of plastics are produced around the world and, by varying the ligands in the catalytically active compounds, the properties of the resulting polymers can even be tailored for use. For this purpose, sandwich compounds from early transition metals have been common until now, but interest has focused increasingly on the late transition metals. In this book, the world's leading authors from research and industry discuss the latest developments in research into palladium, zinc, iron and nickel catalysis. In so doing, they systematically introduce readers to the basic principles and illustrate how these innovative catalysts can be effectively used for polymerizations. The result is an ideal reference work, invaluable for every organic chemist working in catalysis or polymer research.
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At the start of the 1950s, Ziegler and Natta discovered that simple metallorganic catalysts are capable of transforming olefins into linear polymers with highly ordered structures. This pioneering discovery was recognized with a Nobel Prize in 1963. In the 80s and 90s, the development of molecular defined metallocenes led to a renaissance for non–polar polyolefin materials. Designer catalysts allowed a greater precision in defining properties of the material.
The past 10 years have seen the discovery of new catalysts based on late transition metals, which allow the combination of polar monomers with non–polar olefins and thus lead to innovative materials. Here, the world′s leading authors from industry and academia describe the latest developments in this fascinating field for the first time in such comprehensive detail. In so doing, they introduce readers systematically to the basic principles and show how these new catalysts can effectively be used for polymerization reactions. This makes the book an ideal and indispensable reference for specialists, advanced students, and scientists of various disciplines dealing with research into catalysts and materials science.
"This book can be recommended unreservedly for all scientists with an interest in polymerization catalysis...This is an excellent and very up–to–date book!" ( Angewandte Chemie Int. Ed., 2003, 30)
"Thanks to the publisher and the publishing house for this up–to–date and forward looking book." (Albrecht, W., Chemical Fibers International)
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Etat : Gut. Zustand: Gut | Seiten: 345 | Sprache: Englisch | Produktart: Bücher | Keine Beschreibung verfügbar. N° de réf. du vendeur 1039523/203
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