Reactive Extraction - Couverture rigide

Bart, Hans-Jörg

Couverture rigide

ISBN 10 : 3540410872 ISBN 13 : 9783540410874

Editeur : Springer-Verlag Berlin and Heidelberg GmbH & Co. K, 2001

Synopsis

This booklet is designed to bridge the gap between handbooks and technical literature and aims at graduate students or experienced readers. Commercial flow sheeting simulation software is increasingly available and is used in the early steps of process design in industry. As to this, more sophisticated and precise models based on activities instead of concentrations should be used. After an introductory chapter there is in Chapter 2 an intensive discussion of reactive phase equilibria of ionic and non-ionic solutes based on chemical potentials. Chapter 3 introduces to multicomponent diffusion and mass transfer. However, the main focus is on the reactive mass transfer on rigid and mobile surfaces where the interfacial reaction, molecular diffusion and adsorption layers are decisive. The respective extraction of zinc with a cation exchanger and of acetic acid with an anion exchanger is discussed as case studies. Since adsorption layers and surfactants have a major impact on liquid-liquid extraction efficiency, the final chapter reviews several tech- niques which make use of polymeric species in an extractive process. A short review is also given on extraction apparatus and the hydrodynamics (hydraulic design, droplet populance balances) of columns. Much of the booklet is based on the PhD works of C. Czapla (2000), G. Modes (2000), H. Klocker (1996), T. Kronberger (1995), M. Marters (2000), M. Roos (2000), M. Traving (2000) and B. Wachter (1996) who I wish to thank for their fruitful contributions.

A propos du livre

Présentation de l'éditeur

This book is designed to bridge the gap between handbooks and technical literature and is intended to serve the research needs of both academic and industrial scientists and graduate students. It begins with a discussion on reactive extraction systems and provides a state-of-the-art description of phase equilibria in reacting liquid-liquid systems. The following chapter discusses reactive mass transfer with a focus on transfer regimes, surfactant layers, zeta potential and experimental techniques. A brief summary on current developments and not common extraction techniques is also offered. A program for column design which is available from the author's homepage is described in Appendix X, and references to other license-free codes in the web are also given.

Détails de l'édition

• Éditeur: Springer-Verlag Berlin and Heidelberg GmbH & Co. K
• Date d'édition: 2001
• Langue: anglais
• ISBN 10: 3540410872
• ISBN 13: 9783540410874
• Reliure: Relié
• Nombre de pages: 228
• Coordonnées du fabricant: ProductSafety@springernature.com; ProductSafety@springernature.com; ; Poststr. 9; Darmstadt; 64293; Allemagne