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Statistical, Gradient, Block and Graft Copolymers by Controlled/Living Radical Polymerizations - Couverture rigide
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This review is focused on controlled/living radical polymerization methods for the preparation of various copolymers. A brief introduction to the subject of radical polymerization, and early attempts to control it, is followed by a detailed examination of the literautre on controlled/living radical copolymerizations from the mid-90's until 2001. The topics covered include statistical/gradient, block, graft, and star copolymers and the polymerization methods used to produce them. These copolymers were prepared using three major controlled radical methods (either nitroxide mediated polymerization, atom transfer radical polymerization or degenerative transfer) and a combination of polymerization techniques, including transformation chemistry or the simultaneous/dual living polymerizations, to achieve the desired chain architecture or topology. An evaluation of the current state of the field is also presented.
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- ÉditeurSpringer-Verlag Berlin and Heidelberg GmbH & Co. K
- Date d'édition2002
- ISBN 10 3540432442
- ISBN 13 9783540432449
- ReliureRelié
- Nombre de pages192
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Statistical, Gradient, Block and Graft Copolymers by Controlled/Living Radical Polymerizations (Advances in Polymer Science) by Davis, Kelly A., Matyjaszewski, Krzysztof [Hardcover ]
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Description du livre Hardcover. Etat : new. N° de réf. du vendeur 9783540432449
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Statistical, Gradient, Block and Graft Copolymers by Controlled/Living Radical Polymerizations (Advances in Polymer Science)
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Description du livre Etat : New. N° de réf. du vendeur ABLIING23Mar3113020167456
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Statistical, Gradient, Block and Graft Copolymers by Controlled/Living Radical Polymerizations
Edité par
Springer Berlin Heidelberg
(2002)
ISBN 10 : 3540432442
ISBN 13 : 9783540432449
Neuf
Couverture rigide
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Description du livre Etat : New. Dieser Artikel ist ein Print on Demand Artikel und wird nach Ihrer Bestellung fuer Sie gedruckt. Highest Impact Factor of all journals ranked by ISI within Polymer ScienceShort and concise reports on physics and chemistry of polymers, each written by the world renowned expertsStill valid and useful after 5 or 10 yearsThe electronic version . N° de réf. du vendeur 4890337
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Statistical, Gradient, Block and Graft Copolymers by Controlled/Living Radical Polymerizations
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Springer Berlin Heidelberg Aug 2002
(2002)
ISBN 10 : 3540432442
ISBN 13 : 9783540432449
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Description du livre Buch. Etat : Neu. This item is printed on demand - it takes 3-4 days longer - Neuware -The design and the realisation of well defined polymer architectures has become an important goal in macromolecular science. The prerequisite for achieving this goal is the availability of controlled polymerisation reactions. Living anionic polymerisation was the first reaction fulfilling these requirements. Cationic polymerisation only came into play when it was realised that it was possible to create an equilibrium between active and dormant species with the fraction of the dormant species being far superior to that of active ones. A corresponding principle applies to controlled radical polymerisation per formed in quite a number of modes such as nitroxide mediated polymerisation (NMP), atom transfer radical polymerisation (ATRP), reversible addition frag mentation chain transfer (RAFT) or catalytic chain transfer (CCT) reactions. All of these variants of controlled radical polymerisation lead to well defined archi tectures with the particular advantage that a much larger number of monomers are suitable and the reaction conditions are much less demanding than those of living ionic polymerisation reactions. Although in controlled radical polymerisation, termination reactions cannot be excluded completely, they are limited in their extent and consequently the mol ecular weight is controlled, the polydispersity index is small and functionalities can be attached to the macromolecules. These features are indicative of the real isation of well defined polymer architectures such as block copolymers, star shaped and comb shaped copolymers. 204 pp. Englisch. N° de réf. du vendeur 9783540432449
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Statistical, Gradient, Block and Graft Copolymers by Controlled/Living Radical Polymerizations
Edité par
Springer Berlin Heidelberg
(2002)
ISBN 10 : 3540432442
ISBN 13 : 9783540432449
Neuf
Couverture rigide
Quantité disponible : 1
Vendeur :
Evaluation vendeur
Description du livre Buch. Etat : Neu. Druck auf Anfrage Neuware - Printed after ordering - The design and the realisation of well defined polymer architectures has become an important goal in macromolecular science. The prerequisite for achieving this goal is the availability of controlled polymerisation reactions. Living anionic polymerisation was the first reaction fulfilling these requirements. Cationic polymerisation only came into play when it was realised that it was possible to create an equilibrium between active and dormant species with the fraction of the dormant species being far superior to that of active ones. A corresponding principle applies to controlled radical polymerisation per formed in quite a number of modes such as nitroxide mediated polymerisation (NMP), atom transfer radical polymerisation (ATRP), reversible addition frag mentation chain transfer (RAFT) or catalytic chain transfer (CCT) reactions. All of these variants of controlled radical polymerisation lead to well defined archi tectures with the particular advantage that a much larger number of monomers are suitable and the reaction conditions are much less demanding than those of living ionic polymerisation reactions. Although in controlled radical polymerisation, termination reactions cannot be excluded completely, they are limited in their extent and consequently the mol ecular weight is controlled, the polydispersity index is small and functionalities can be attached to the macromolecules. These features are indicative of the real isation of well defined polymer architectures such as block copolymers, star shaped and comb shaped copolymers. N° de réf. du vendeur 9783540432449
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Statistical, Gradient, Block and Graft Copolymers by Controlled/Living Radical Polymerizations
Edité par
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(2002)
ISBN 10 : 3540432442
ISBN 13 : 9783540432449
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Description du livre Etat : New. pp. 208. N° de réf. du vendeur 263067508
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Statistical, Gradient, Block and Graft Copolymers by Controlled/Living Radical Polymerizations
Edité par
Springer
(2002)
ISBN 10 : 3540432442
ISBN 13 : 9783540432449
Neuf
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Description du livre Etat : New. Print on Demand pp. 208 126 Illus. N° de réf. du vendeur 5861803
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Statistical; Gradient; Block and Graft Copolymers by Controlled/Living Radical Polymerizations
Edité par
Springer
(2002)
ISBN 10 : 3540432442
ISBN 13 : 9783540432449
Neuf
Couverture rigide
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Description du livre Etat : New. PRINT ON DEMAND Book; New; Fast Shipping from the UK. No. book. N° de réf. du vendeur ria9783540432449_lsuk
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