Three-Dimensional Free-Radical Polymerization. Cross-Linked Polymers.- Microheterogeneous Mechanism of Three-Dimensional Free-Radical Polymerization.- Kinetic Features of Three-Dimensional Free-Radical Polymerization.- Living Chain Three-Dimensional Radical Polymerization.- Kinetic Features of Three-Dimensional Free-Radical Copolymerization.- Critical Conversion (Gel Point) in Three-Dimensional Free-Radical Polymerization.- Properties of Cross-Linked Polymers and Copolymers.- Three-Dimensional Free-Radical Polymerization. Hyper-Branched Polymers.- Synthesis of Hyper-Branched Polymers.- Properties and Application of Hyper-Branched Polymers.- Methods for Studying Three-Dimensional Free-Radical Polymerization and Cross-Linked Polymers.
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The book discusses the latest developments in the entire field of three-dimensional free-radical polymerization, the scientific and practical aspects thereof, as well as the achievements, problems, methods used in the field, and modern development trends. The monograph is comprised of nine chapters and provides 747 references. The book is a necessary reading for both teachers and students because it connects the basics of the synthesis of cross-linked and hyper-branched polymers with their physico-mechanical properties, and concisely explains practical achievements in this branch of polymer chemistry.
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Etat : Sehr gut. Zustand: Sehr gut | Seiten: 288 | Sprache: Englisch | Produktart: Bücher | At present, three-dimensional free-radical polymerization (TFRP) is a special ?eld of radical polymerization. TFRP is characterized by speci?c kinetic regularities and mechanisms of processes for the formation of cross-linked or hyper-branched po- mers, and they are different from the kinetics and mechanism of classical radical polymerization. The fundamental studies of kinetics and mechanism of TFRP with formation of cross-linked polymers have been carried out in three stages. The ?rst stage lasted from 1960 until 1983, and the main mechanisms of TFRP of oligo(acrylates) were established during this stage [1¿3]. Condensation telomerization, being a universal oligo(acrylate) synthesis procedure, allows us to vary certain molecular parameters, such as length and ?exibility of oligomeric blocks, number and type of reactive groups (methacrylic or acrylic groups), and chemical nature of atomic groups of an oligomeric block, which represent the centers of strong intermolecular interactions. For this reason, oligo(acrylates) were very convenient compounds for establi- ing the main kinetic regularities of TFRP and regularities of formation of polymer three-dimensional cross-linkedstructures,according totheso-calledmicrohetero- neous mechanism (G.V. Korolev, 1977), at the topological and morphological levels. N° de réf. du vendeur 4680337/12
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Buch. Etat : Neu. This item is printed on demand - it takes 3-4 days longer - Neuware -At present, three-dimensional free-radical polymerization (TFRP) is a special eld of radical polymerization. TFRP is characterized by speci c kinetic regularities and mechanisms of processes for the formation of cross-linked or hyper-branched po- mers, and they are different from the kinetics and mechanism of classical radical polymerization. The fundamental studies of kinetics and mechanism of TFRP with formation of cross-linked polymers have been carried out in three stages. The rst stage lasted from 1960 until 1983, and the main mechanisms of TFRP of oligo(acrylates) were established during this stage [1 3]. Condensation telomerization, being a universal oligo(acrylate) synthesis procedure, allows us to vary certain molecular parameters, such as length and exibility of oligomeric blocks, number and type of reactive groups (methacrylic or acrylic groups), and chemical nature of atomic groups of an oligomeric block, which represent the centers of strong intermolecular interactions. For this reason, oligo(acrylates) were very convenient compounds for establi- ing the main kinetic regularities of TFRP and regularities of formation of polymer three-dimensional cross-linkedstructures,according totheso-calledmicrohetero- neous mechanism (G.V. Korolev, 1977), at the topological and morphological levels. 288 pp. Englisch. N° de réf. du vendeur 9783540875666
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Etat : New. Dieser Artikel ist ein Print on Demand Artikel und wird nach Ihrer Bestellung fuer Sie gedruckt. First book on the subject comprising the research results of the last 40 yearsIncludes synthesis, mechanism and physico-mechanical properties, thus important for the specialist in new hightech areasThree-Dimensional Free-Radical Polymeriza. N° de réf. du vendeur 4901673
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Buch. Etat : Neu. This item is printed on demand - Print on Demand Titel. Neuware -At present, three-dimensional free-radical polymerization (TFRP) is a special eld of radical polymerization. TFRP is characterized by speci c kinetic regularities and mechanisms of processes for the formation of cross-linked or hyper-branched po- mers, and they are different from the kinetics and mechanism of classical radical polymerization. The fundamental studies of kinetics and mechanism of TFRP with formation of cross-linked polymers have been carried out in three stages. The rst stage lasted from 1960 until 1983, and the main mechanisms of TFRP of oligo(acrylates) were established during this stage [1¿3]. Condensation telomerization, being a universal oligo(acrylate) synthesis procedure, allows us to vary certain molecular parameters, such as length and exibility of oligomeric blocks, number and type of reactive groups (methacrylic or acrylic groups), and chemical nature of atomic groups of an oligomeric block, which represent the centers of strong intermolecular interactions. For this reason, oligo(acrylates) were very convenient compounds for establi- ing the main kinetic regularities of TFRP and regularities of formation of polymer three-dimensional cross-linkedstructures,according totheso-calledmicrohetero- neous mechanism (G.V. Korolev, 1977), at the topological and morphological levels.Springer-Verlag GmbH, Tiergartenstr. 17, 69121 Heidelberg 288 pp. Englisch. N° de réf. du vendeur 9783540875666
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Buch. Etat : Neu. Druck auf Anfrage Neuware - Printed after ordering - At present, three-dimensional free-radical polymerization (TFRP) is a special eld of radical polymerization. TFRP is characterized by speci c kinetic regularities and mechanisms of processes for the formation of cross-linked or hyper-branched po- mers, and they are different from the kinetics and mechanism of classical radical polymerization. The fundamental studies of kinetics and mechanism of TFRP with formation of cross-linked polymers have been carried out in three stages. The rst stage lasted from 1960 until 1983, and the main mechanisms of TFRP of oligo(acrylates) were established during this stage [1 3]. Condensation telomerization, being a universal oligo(acrylate) synthesis procedure, allows us to vary certain molecular parameters, such as length and exibility of oligomeric blocks, number and type of reactive groups (methacrylic or acrylic groups), and chemical nature of atomic groups of an oligomeric block, which represent the centers of strong intermolecular interactions. For this reason, oligo(acrylates) were very convenient compounds for establi- ing the main kinetic regularities of TFRP and regularities of formation of polymer three-dimensional cross-linkedstructures,according totheso-calledmicrohetero- neous mechanism (G.V. Korolev, 1977), at the topological and morphological levels. N° de réf. du vendeur 9783540875666
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