Late Transition Metal-carboryne Complexes: Synthesis, Structure, Bonding, and Reaction With Alkenes and Alkynes - Couverture rigide

Qiu, Zaozao

 
9783642243608: Late Transition Metal-carboryne Complexes: Synthesis, Structure, Bonding, and Reaction With Alkenes and Alkynes

Synopsis

Zaozao Qiu shows in this thesis that transition metals can mediate or catalyze the cycloaddition or coupling reactions of carboryne with alkynes or alkenes to afford benzocarboranes, alkenylcarboranes or dihydrobenzocarboranes. These results represent powerful strategies to assemble useful complex molecules from very simple precursors in a single operation. Carboranes have many applications in medicine. However, their unique structures make derivatization difficult and the limited efficient synthetic methods to obtain functional carborane materials have restricted applications of carboranes within a narrow scope. This work breaks a new ground in metal-carboryne chemistry and will have a significant impact on synthetic, cluster and materials chemistry.

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Autres éditions populaires du même titre

9783642435027: Late Transition Metal-Carboryne Complexes: Synthesis, Structure, Bonding, and Reaction with Alkenes and Alkynes

Edition présentée

ISBN 10 :  3642435025 ISBN 13 :  9783642435027
Editeur : Springer, 2014
Couverture souple