L'effet du champ magnétique sur la luminescence exciplex pyrène/N, N-diméthylaniline a été étudié. Le concept d'exciplex non détendus (émettant à l'extrémité bleue de la bande d'émission) et détendus dans les solvants polaires a été introduit. La désintégration bi-exponentielle du pyrène en phase condensée a été établie, ce qui est expliqué sur la base de la formation complexe de pyrène excitée avec des molécules de solvant. La mesure des valeurs B1/2 du système exciplex dans divers solvants nets et binaires met en lumière la taille des micro-domaines transitoires enrichis en diélectrique dans les solvants binaires autour de la paire d'ions radicaux (RIP) après transfert d'électrons. Les études à vie de l'émission exciplex à divers solvants propres et binaires de permittivité variable reflètent la possibilité d'abaisser l'énergie de la paire d'ions radicaux en dessous de celle du triplet pyrène excité à une permittivité très élevée. Enfin, divers détails d'instrumentation et astuces électroniques pour obtenir un rapport signal sur bruit élevé dans les mesures d'effet de champ magnétique utilisant la technique de verrouillage ont été discutés.
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Vendeur : BuchWeltWeit Ludwig Meier e.K., Bergisch Gladbach, Allemagne
Taschenbuch. Etat : Neu. This item is printed on demand - it takes 3-4 days longer - Neuware -Magnetic field effect on pyrene/N,N-dimethylaniline exciplex luminescence has been studied. Concept of un-relaxed (emitting at the blue end of the emission band) and relaxed exciplexes in polar solvents has been introduced. Bi-exponential decay of pyrene in condensed phase has been established which is explained on the basis of complex formation of excited pyrene with solvent molecules. The measurement of B1/2 values of the exciplex system in various neat and binary solvents throws light on the size of the transient, dielectric enriched micro-domains in binary solvents around the radical ion pair (RIP) after electron transfer. Life-time studies of the exciplex emission at various neat and binary solvents of varying permittivity reflect the possibility of lowering of radical ion pair energy below that of excited triplet pyrene at very high permittivity. Finally various instrumentation detail and electronic tricks to achieve high signal to noise ratio in magnetic field effect measurements employing lock-in technique has been discussed. 168 pp. Englisch. N° de réf. du vendeur 9783659647772
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Vendeur : moluna, Greven, Allemagne
Etat : New. Dieser Artikel ist ein Print on Demand Artikel und wird nach Ihrer Bestellung fuer Sie gedruckt. Autor/Autorin: Nath Deb NarayanPROF.DR.DEB NARAYAN NATHSenior Professor Department of Physical Chemistry IACSJadavpur, Kolkata 700 032,India Born April 30, 1955, Kolkata. Ph.D. (1989), Jadavpur University, Supervisor:Prof. M. Chowdhury, IACS. Rese. N° de réf. du vendeur 5170858
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Vendeur : buchversandmimpf2000, Emtmannsberg, BAYE, Allemagne
Taschenbuch. Etat : Neu. This item is printed on demand - Print on Demand Titel. Neuware -Magnetic field effect on pyrene/N,N-dimethylaniline exciplex luminescence has been studied. Concept of un-relaxed (emitting at the blue end of the emission band) and relaxed exciplexes in polar solvents has been introduced. Bi-exponential decay of pyrene in condensed phase has been established which is explained on the basis of complex formation of excited pyrene with solvent molecules. The measurement of B1/2 values of the exciplex system in various neat and binary solvents throws light on the size of the transient, dielectric enriched micro-domains in binary solvents around the radical ion pair (RIP) after electron transfer. Life-time studies of the exciplex emission at various neat and binary solvents of varying permittivity reflect the possibility of lowering of radical ion pair energy below that of excited triplet pyrene at very high permittivity. Finally various instrumentation detail and electronic tricks to achieve high signal to noise ratio in magnetic field effect measurements employing lock-in technique has been discussed.VDM Verlag, Dudweiler Landstraße 99, 66123 Saarbrücken 168 pp. Englisch. N° de réf. du vendeur 9783659647772
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Vendeur : AHA-BUCH GmbH, Einbeck, Allemagne
Taschenbuch. Etat : Neu. nach der Bestellung gedruckt Neuware - Printed after ordering - Magnetic field effect on pyrene/N,N-dimethylaniline exciplex luminescence has been studied. Concept of un-relaxed (emitting at the blue end of the emission band) and relaxed exciplexes in polar solvents has been introduced. Bi-exponential decay of pyrene in condensed phase has been established which is explained on the basis of complex formation of excited pyrene with solvent molecules. The measurement of B1/2 values of the exciplex system in various neat and binary solvents throws light on the size of the transient, dielectric enriched micro-domains in binary solvents around the radical ion pair (RIP) after electron transfer. Life-time studies of the exciplex emission at various neat and binary solvents of varying permittivity reflect the possibility of lowering of radical ion pair energy below that of excited triplet pyrene at very high permittivity. Finally various instrumentation detail and electronic tricks to achieve high signal to noise ratio in magnetic field effect measurements employing lock-in technique has been discussed. N° de réf. du vendeur 9783659647772
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Vendeur : preigu, Osnabrück, Allemagne
Taschenbuch. Etat : Neu. Studies of exciplex system in condensed phase:Magnetic field effect | Researches on exciplex emission in condensed phase at Indian Association For The Cultivation of Science, Kolkata, India | Deb Narayan Nath (u. a.) | Taschenbuch | 168 S. | Englisch | 2015 | LAP LAMBERT Academic Publishing | EAN 9783659647772 | Verantwortliche Person für die EU: BoD - Books on Demand, In de Tarpen 42, 22848 Norderstedt, info[at]bod[dot]de | Anbieter: preigu. N° de réf. du vendeur 104936186
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