S Sulfur-nitrogen Compounds: Compounds With Sulfur of Oxidation Number IV - Couverture souple

Baumann, Norbert; Fachmann, Hans-Jürgen; Heibel, Brigitte; Jotter, Reimund; Ledüc, Birgit

Couverture souple

ISBN 10 : 3662063654 ISBN 13 : 9783662063651

Editeur : Springer-Verlag Berlin and Heidelberg GmbH & Co. K, 2013

Synopsis

PF3, (CH3)3SiCl -> (CH3)3SiF, and RC(O)Cl -> RC(O)F. Others include the conversion of (C6H5)3P into (C6H5)3PF2 and of (R3NC(S)S)2 into R2NCF3, R=alkyl. In organic chemistry, fluorides are easily accessible from alcohols, geminal fluorides RR'CF2 from the respective aldehydes or ketones, and acyl fluorides RC(O)F from carboxylic acides by using DAST. Because DAST is easy to handle and gives clean reactions in syntheses, this Gmelin volume devotes much space to the description of the chemical and physical properties od DAST.

Détails de l'édition

• Éditeur: Springer-Verlag Berlin and Heidelberg GmbH & Co. K
• Date d'édition: 2013
• Langue: anglais
• ISBN 10: 3662063654
• ISBN 13: 9783662063651
• Reliure: Broché
• Nombre de pages: 518
• Éditeur: Baumann Norbert, Kubny Alfons, Fachmann Hans-Jürgen, Heibel Brigitte, Jotter Reimund
• Coordonnées du fabricant: Springer Nature Customer Service Center GmbH; ProductSafety@springernature.com; ; Europaplatz 3,69115 Heidelberg, Germany; Heidelberg; 69115; Allemagne