Studies of New Pyrazolate-Based Binuclear Ruthenium Complexes for Catalytic Water Oxidation - Couverture souple

Sander, Anett Carolin

9783736991866: Studies of New Pyrazolate-Based Binuclear Ruthenium Complexes for Catalytic Water Oxidation

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ISBN 10 : 373699186X ISBN 13 : 9783736991866

Editeur : Cuvillier, 2016

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�diteur: Cuvillier
Date d'�dition: 2016
Langue: anglais
ISBN 10: 373699186X
ISBN 13: 9783736991866
Reliure: Broch�
Nombre de pages: 284
Coordonn�es du fabricant: GPSR Kontakt
info@cuvillier.de

Nonnenstieg 8
G�ttingen
37075
Allemagne

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Studies of New Pyrazolate-Based Binuclear Ruthenium Complexes for Catalytic Water Oxidation

Sander, Anett Carolin

Edit� par Cuvillier, 2016

ISBN 10 : 373699186X ISBN 13 : 9783736991866

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Studies of New Pyrazolate-Based Binuclear Ruthenium Complexes for Catalytic Water Oxidation

Sander, Anett Carolin

Edit� par Cuvillier, 2016

ISBN 10 : 373699186X ISBN 13 : 9783736991866

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Studies of New Pyrazolate-Based Binuclear Ruthenium Complexes for Catalytic Water Oxidation

Sander, Anett Carolin

Edit� par Cuvillier, 2016

ISBN 10 : 373699186X ISBN 13 : 9783736991866

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Studies of New Pyrazolate-Based Binuclear Ruthenium Complexes for Catalytic Water Oxidation

Anett Carolin Sander

Edit� par Cuvillier Jan 2016, 2016

ISBN 10 : 373699186X ISBN 13 : 9783736991866

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Taschenbuch. Etat : Neu. This item is printed on demand - it takes 3-4 days longer - Neuware -The world�s energy consumption is predicted to increase significantly over the coming decades. Diminishing fossil energy resources and the target to reduce greenhouse gas emission make new technologies a necessity to meet future energy demands. Thus, the exploitation of renewable energy sources is of prime interest in chemical research today. In nature, photosynthesis uses solar energy to split water, generating protons and reducing equivalents for the production of organic material. The oxidative half-reaction of water splitting, that is, the generation of dioxygen, is a thermodynamically and kinetically demanding 4e-/4H+ process and is therefore considered to be the bottleneck of this approach. Developing rugged and highly efficient catalysts for this water oxidation reaction is a major challenge in this research field.The herein presented work introduces a number of new rationally designed pyrazolate-based diruthenium complexes as water oxidation catalysts, emphasizing the favourable preorganisation of two metal ions in one system for binding of two water molecules at a distance adequate for O-O bond formation. Thorough characterisation of the complexes using a wide range of analytical techniques and fundamental investigation of water oxidation catalysis � both chemically and electrochemically � allow deep insight into the water oxidation reaction and influences of different ligand designs on catalytic performances. The results described in this work contribute to a better understanding of the possibility to rationally design water oxidation catalysts on a molecular basis. 284 pp. Englisch. N� de r�f. du vendeur 9783736991866

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Studies of New Pyrazolate-Based Binuclear Ruthenium Complexes for Catalytic Water Oxidation

Sander, Anett Carolin

Edit� par Cuvillier Verlag, 2016

ISBN 10 : 373699186X ISBN 13 : 9783736991866

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Studies of New Pyrazolate-Based Binuclear Ruthenium Complexes for Catalytic Water Oxidation

Anett Carolin Sander

Edit� par Cuvillier, Cuvillier Jan 2016, 2016

ISBN 10 : 373699186X ISBN 13 : 9783736991866

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Taschenbuch. Etat : Neu. This item is printed on demand - Print on Demand Titel. Neuware -The world's energy consumption is predicted to increase significantly over the coming decades. Diminishing fossil energy resources and the target to reduce greenhouse gas emission make new technologies a necessity to meet future energy demands. Thus, the exploitation of renewable energy sources is of prime interest in chemical research today. In nature, photosynthesis uses solar energy to split water, generating protons and reducing equivalents for the production of organic material. The oxidative half-reaction of water splitting, that is, the generation of dioxygen, is a thermodynamically and kinetically demanding 4e-/4H+ process and is therefore considered to be the bottleneck of this approach. Developing rugged and highly efficient catalysts for this water oxidation reaction is a major challenge in this research field.The herein presented work introduces a number of new rationally designed pyrazolate-based diruthenium complexes as water oxidation catalysts, emphasizing the favourable preorganisation of two metal ions in one system for binding of two water molecules at a distance adequate for O-O bond formation. Thorough characterisation of the complexes using a wide range of analytical techniques and fundamental investigation of water oxidation catalysis - both chemically and electrochemically - allow deep insight into the water oxidation reaction and influences of different ligand designs on catalytic performances. The results described in this work contribute to a better understanding of the possibility to rationally design water oxidation catalysts on a molecular basis.Cuvillier Verlag, Nonnenstieg 8, 37075 G�ttingen 284 pp. Englisch. N� de r�f. du vendeur 9783736991866

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Studies of New Pyrazolate-Based Binuclear Ruthenium Complexes for Catalytic Water Oxidation

Anett Carolin Sander

Edit� par Cuvillier, 2016

ISBN 10 : 373699186X ISBN 13 : 9783736991866

Neuf Taschenbuch

impression � la demande

Vendeur : AHA-BUCH GmbH, Einbeck, Allemagne

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Taschenbuch. Etat : Neu. nach der Bestellung gedruckt Neuware - Printed after ordering - The world�s energy consumption is predicted to increase significantly over the coming decades. Diminishing fossil energy resources and the target to reduce greenhouse gas emission make new technologies a necessity to meet future energy demands. Thus, the exploitation of renewable energy sources is of prime interest in chemical research today. In nature, photosynthesis uses solar energy to split water, generating protons and reducing equivalents for the production of organic material. The oxidative half-reaction of water splitting, that is, the generation of dioxygen, is a thermodynamically and kinetically demanding 4e-/4H+ process and is therefore considered to be the bottleneck of this approach. Developing rugged and highly efficient catalysts for this water oxidation reaction is a major challenge in this research field.The herein presented work introduces a number of new rationally designed pyrazolate-based diruthenium complexes as water oxidation catalysts, emphasizing the favourable preorganisation of two metal ions in one system for binding of two water molecules at a distance adequate for O-O bond formation. Thorough characterisation of the complexes using a wide range of analytical techniques and fundamental investigation of water oxidation catalysis � both chemically and electrochemically � allow deep insight into the water oxidation reaction and influences of different ligand designs on catalytic performances. The results described in this work contribute to a better understanding of the possibility to rationally design water oxidation catalysts on a molecular basis. N� de r�f. du vendeur 9783736991866

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