A New Approach Towards Multiproperty Molecular Materials: Combining Interesting Magnetic, Electric and Second-Order Nonlinear Optical Properties. Ferrocene-Based Polychlorotriphenylmethyl Radicals - Couverture souple

Ratera, Imma

 
9783838313191: A New Approach Towards Multiproperty Molecular Materials: Combining Interesting Magnetic, Electric and Second-Order Nonlinear Optical Properties. Ferrocene-Based Polychlorotriphenylmethyl Radicals
Couverture souple
ISBN 10 : 3838313194 ISBN 13 : 9783838313191
Editeur : LAP LAMBERT Academic Publishing, 2010

Synopsis

This is part of a general effort aimed at extending the range of molecular materials combining two properties in the same molecule and their tuning by changing the different electron ability of the metallocene and the radical units. The magnetic properties of different mono, bi and tri radicals have been studied.In addition, an interesting example of a photomagnetic system based on a supramolecular phenomenon in which a doublet species is converted into a singlet one is presented. Such ferrocene-polychlorotriphenylmethyl radicals present intramolecular electron transfer phenomenon which energy can be easily tuned by changing the substitutents of the donor or acceptor units or even the nature of the solvent. It is also described a novel valence tautomeric example combining an organic radical as acceptor unit and a ferrocene unit as the donor group. Finally, it has been proved that Ferrocene based polychlorotriphenylmethyl radicals systems also exhibits intense NLO responses that can be modulated at will simply tuning the donor and acceptor capabilities of the ferrocene and radical units.

Les informations fournies dans la section « Synopsis » peuvent faire référence à une autre édition de ce titre.

Présentation de l'éditeur

This is part of a general effort aimed at extending the range of molecular materials combining two properties in the same molecule and their tuning by changing the different electron ability of the metallocene and the radical units. The magnetic properties of different mono, bi and tri radicals have been studied.In addition, an interesting example of a photomagnetic system based on a supramolecular phenomenon in which a doublet species is converted into a singlet one is presented. Such ferrocene-polychlorotriphenylmethyl radicals present intramolecular electron transfer phenomenon which energy can be easily tuned by changing the substitutents of the donor or acceptor units or even the nature of the solvent. It is also described a novel valence tautomeric example combining an organic radical as acceptor unit and a ferrocene unit as the donor group. Finally, it has been proved that Ferrocene based polychlorotriphenylmethyl radicals systems also exhibits intense NLO responses that can be modulated at will simply tuning the donor and acceptor capabilities of the ferrocene and radical units.

Biographie de l'auteur

Imma Ratera: Chemistry at Universitat de Barcelona and PhD in Materials Science at UAB and Institut of Materials Science of Barcelona (ICMAB-CSIC) working with Prof.J.Veciana and Dr.D.Ruiz- Molina. In 2003 she joined Prof.M.Salmeron?s Group at Lawrence Berkeley National Laboratory. Since May 2005, she works as a researcher at ICMAB.

Les informations fournies dans la section « A propos du livre » peuvent faire référence à une autre édition de ce titre.

Éditeur
LAP LAMBERT Academic Publishing
Date d'édition
2010
Langue
anglais
ISBN 10 
3838313194
ISBN 13 
9783838313191
Reliure
Broché
Nombre de pages
208
Coordonnées du fabricant
non disponible
Personne responsable
non disponible