Switching From Homogeneous To Heterogeneous Catalysis: Struggle for Asymmetric Heterogeneous Catalysis - Couverture souple

Sadiq, Mohammad; Aman, Razia

 
9783838350394: Switching From Homogeneous To Heterogeneous Catalysis: Struggle for Asymmetric Heterogeneous Catalysis
Couverture souple
ISBN 10 : 3838350391 ISBN 13 : 9783838350394
Editeur : LAP LAMBERT Academic Publishing, 2012

Synopsis

Direct aldol reactions have been successfully performed using aromatic aldehyde and cyclic ketone in nonpolar/polar solvent using immobilized picolylamine on zirconia as a catalyst, in a double walled three necked batch reactor. The prepared catalyst was characterized by SEM, XRD and FT-IR. FT-IR peaks reveal the presence of picolylamine on the surface of zirconia. The catalyst show excellent catalytic activity in aldol reaction of cyclohexanone with benzaldehyde in cyclohexane giving (2-hydroxy phenyl methyl cyclohexanone) (55.7% yields) in 4 hours at 80°C. Furthermore, the catalyst is recoverable by simple filtration and could be used several times without significant loss in activity. In addition the chiral amine will be anchor on the surface of zirconia for asymmetric aldol reaction in future studies.

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Présentation de l'éditeur

Direct aldol reactions have been successfully performed using aromatic aldehyde and cyclic ketone in nonpolar/polar solvent using immobilized picolylamine on zirconia as a catalyst, in a double walled three necked batch reactor. The prepared catalyst was characterized by SEM, XRD and FT-IR. FT-IR peaks reveal the presence of picolylamine on the surface of zirconia. The catalyst show excellent catalytic activity in aldol reaction of cyclohexanone with benzaldehyde in cyclohexane giving (2-hydroxy phenyl methyl cyclohexanone) (55.7% yields) in 4 hours at 80°C. Furthermore, the catalyst is recoverable by simple filtration and could be used several times without significant loss in activity. In addition the chiral amine will be anchor on the surface of zirconia for asymmetric aldol reaction in future studies.

Biographie de l'auteur

Dr. M. Sadiq joined Department of Chemistry, University of Malakand as assistant professor in 2010. His research interests include heterogeneous catalysis, especially, developing asymmetric heterogeneous catalysts for different organic reactions.

Les informations fournies dans la section « A propos du livre » peuvent faire référence à une autre édition de ce titre.

Éditeur
LAP LAMBERT Academic Publishing
Date d'édition
2012
Langue
anglais
ISBN 10 
3838350391
ISBN 13 
9783838350394
Reliure
Broché
Nombre de pages
52
Coordonnées du fabricant
non disponible
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