Rotational Spectra of Elusive Molecules in the Laboratory and in Space - Couverture souple

Spezzano, Silvia

9783954047611: Rotational Spectra of Elusive Molecules in the Laboratory and in Space

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ISBN 10 : 3954047616 ISBN 13 : 9783954047611

Editeur : Cuvillier Verlag, 2014

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�diteur: Cuvillier Verlag
Date d'�dition: 2014
Langue: anglais
ISBN 10: 3954047616
ISBN 13: 9783954047611
Reliure: Broch�
Nombre de pages: 142
Coordonn�es du fabricant: info@cuvillier.de
info@cuvillier.de

Nonnenstieg 8
G�ttingen
37075
Allemagne

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Rotational Spectra of Elusive Molecules in the Laboratory and in Space

Spezzano, Silvia

ISBN 10 : 3954047616 ISBN 13 : 9783954047611

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Rotational Spectra of Elusive Molecules in the Laboratory and in Space

Spezzano, Silvia

Edit� par Cuvillier, 2014

ISBN 10 : 3954047616 ISBN 13 : 9783954047611

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Rotational Spectra of Elusive Molecules in the Laboratory and in Space

Silvia Spezzano

Edit� par Cuvillier Jul 2014, 2014

ISBN 10 : 3954047616 ISBN 13 : 9783954047611

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Taschenbuch. Etat : Neu. This item is printed on demand - it takes 3-4 days longer - Neuware -Molecules are important tools to unveil the history, the structure and the evolution of the Universe. In this thesis I underline the importance of high resolution spectroscopy in the laboratory and in space, and the symbiotic bond between laboratory spectroscopy and radioastronomy. My work is divided in two parts. The first part concerns high resolution spectroscopy of unstable molecules in the laboratory. The second part deals with radioastronomical observations of deuterated molecules in dense cores.The rotational spectra of CO+, 13CO+ and C18O+ in the v = 0 and 1 vibrational states have been measured in the submillimeter-wave range. Furthermore, the first THz spectra of the main isotopic species have been measured. An isotopically invariant fit has been performed, and a set of independent molecular parameters has been derived. The measured and predicted high frequency transitions of CO+ will guide new astronomical observations. Furthermore, an experimental setup to produce and probe ions in the laboratory, based on a new cryogenic discharge cell, has been developed and tested. The new experiment is presented, and some possible implementations for the future are discussed.The doubly deuterated cyclopropenylidene, c-C3D2, has been detected for the first time in space toward the starless cores TMC-1C and L1544. The chemistry that leads to the formation of c-C3D2 has been studied and is discussed in this thesis. The observed abundances c-C3D2 can be explained solely by gas-phase processes, supporting the idea that c-C3H2 is an excellent probe of gas-phase deuteration. Furthermore, l-C3HD has been tentatively detected towards TMC-1C and L1544. l-C3HD is the monodeuterated isotopologue of the linear isomer of cyclopropenylidene, propadienylidene. 142 pp. Englisch. N� de r�f. du vendeur 9783954047611

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Rotational Spectra of Elusive Molecules in the Laboratory and in Space

Spezzano, Silvia

Edit� par Cuvillier Verlag, 2014

ISBN 10 : 3954047616 ISBN 13 : 9783954047611

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Kartoniert / Broschiert. Etat : New. Dieser Artikel ist ein Print on Demand Artikel und wird nach Ihrer Bestellung fuer Sie gedruckt. KlappentextrnrnMolecules are important tools to unveil the history, the structure and the evolution of the Universe. In this thesis I underline the importance of high resolution spectroscopy in the laboratory and in space, and the symbiotic bond. N� de r�f. du vendeur 117181726

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Rotational Spectra of Elusive Molecules in the Laboratory and in Space

Silvia Spezzano

Edit� par Cuvillier

ISBN 10 : 3954047616 ISBN 13 : 9783954047611

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Vendeur : AHA-BUCH GmbH, Einbeck, Allemagne

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Taschenbuch. Etat : Neu. nach der Bestellung gedruckt Neuware - Printed after ordering - Molecules are important tools to unveil the history, the structure and the evolution of the Universe. In this thesis I underline the importance of high resolution spectroscopy in the laboratory and in space, and the symbiotic bond between laboratory spectroscopy and radioastronomy. My work is divided in two parts. The first part concerns high resolution spectroscopy of unstable molecules in the laboratory. The second part deals with radioastronomical observations of deuterated molecules in dense cores.The rotational spectra of CO+, 13CO+ and C18O+ in the v = 0 and 1 vibrational states have been measured in the submillimeter-wave range. Furthermore, the first THz spectra of the main isotopic species have been measured. An isotopically invariant fit has been performed, and a set of independent molecular parameters has been derived. The measured and predicted high frequency transitions of CO+ will guide new astronomical observations. Furthermore, an experimental setup to produce and probe ions in the laboratory, based on a new cryogenic discharge cell, has been developed and tested. The new experiment is presented, and some possible implementations for the future are discussed.The doubly deuterated cyclopropenylidene, c-C3D2, has been detected for the first time in space toward the starless cores TMC-1C and L1544. The chemistry that leads to the formation of c-C3D2 has been studied and is discussed in this thesis. The observed abundances c-C3D2 can be explained solely by gas-phase processes, supporting the idea that c-C3H2 is an excellent probe of gas-phase deuteration. Furthermore, l-C3HD has been tentatively detected towards TMC-1C and L1544. l-C3HD is the monodeuterated isotopologue of the linear isomer of cyclopropenylidene, propadienylidene. N� de r�f. du vendeur 9783954047611

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