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Branched 2-amino-1, 3-dicyanocyclopenta-1, 3-diene: Synthesis and structural properties - Couverture souple
Synopsis
Reaction of 2-chloroisobutyrophenone with two equivalents of malononitrile anion furnishes 2-amino-1,3-dicyano-5,5-dimethyl-4-phenylcyclopenta-1,3-diene. The cyclic compound represents the novel 2-amino-1,3-dicyanocyclopentadiene structure. The unique 1-cyano-2-amino-3-cyano arrangement in a cyclopentadienic ring brings about a strong polarization of the electronic configuration of the diene π system that is conformed by two opposite dipolar halves as revealed by IR and 13C NMR data for the compound. Such polarized configuration accounts for the extreme persistence manifested by the compound in contrast with unsubstituted cyclopentadiene. The cyclopentadiene owns a vivid lemon-hued yellow color consequent to an unusually intense n → π∗ absorption of a cyano group in the extensively conjugated compound. It owns odd photophysical characteristics connected with the arrangement of amino and cyano groups in the diene ring. The compound is built up by consecutive one-pot reaction of two molecules of malononitrile carbanion and a ketonic substrate, and the reaction mechanism continues by a new type of tandem carbon-carbon cyclization that comprises a final elimination of cyanate ion.<p>Reaction of 2-chloroisobutyrophenone with two equivalents of malononitrile anion furnishes 2-amino-1,3-dicyano-5,5-dimethyl-4-phenylcyclopenta-1,3-diene. The cyclic compound represents the novel 2-amino-1,3-dicyanocyclopentadiene structure. The unique 1-cyano-2-amino-3-cyano arrangement in a cyclopentadienic ring brings about a strong polarization of the electronic configuration of the diene π system that is conformed by two opposite dipolar halves as revealed by IR and 13C NMR data for the compound. Such polarized configuration accounts for the extreme persistence manifested by the compound in contrast with unsubstituted cyclopentadiene. The cyclopentadiene owns a vivid lemon-hued yellow color consequent to an unusually intense n → π∗ absorption of a cyano group in the extensively conjugated compound. It owns odd photophysical characteristics connected with the arrangement of amino and cyano groups in the diene ring. The compound is built up by consecutive one-pot reaction of two molecules of malononitrile carbanion and a ketonic substrate, and the reaction mechanism continues by a new type of tandem carbon-carbon cyclization that comprises a final elimination of cyanate ion.</p>
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Branched 2-amino-1, 3-dicyanocyclopenta-1, 3-diene
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LAP LAMBERT Academic Publishing, 2021
ISBN 10 : 6203923826
ISBN 13 : 9786203923827
Neuf
Couverture souple
Vendeur : moluna, Greven, Allemagne
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Branched 2-amino-1, 3-dicyanocyclopenta-1, 3-diene
Edité par
LAP LAMBERT Academic Publishing Jun 2021, 2021
ISBN 10 : 6203923826
ISBN 13 : 9786203923827
Neuf
Taschenbuch
Vendeur : BuchWeltWeit Ludwig Meier e.K., Bergisch Gladbach, Allemagne
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Taschenbuch. Etat : Neu. This item is printed on demand - it takes 3-4 days longer - Neuware -Reaction of 2-chloroisobutyrophenone with two equivalents of malononitrile anion furnishes 2-amino-1,3-dicyano-5,5-dimethyl-4-phenylcyclopenta-1,3-diene. The cyclic compound represents the novel 2-amino-1,3-dicyanocyclopentadiene structure. The unique 1-cyano-2-amino-3-cyano arrangement in a cyclopentadienic ring brings about a strong polarization of the electronic configuration of the diene pi system that is conformed by two opposite dipolar halves as revealed by IR and 13C NMR data for the compound. Such polarized configuration accounts for the extreme persistence manifested by the compound in contrast with unsubstituted cyclopentadiene. The cyclopentadiene owns a vivid lemon-hued yellow color consequent to an unusually intense n pi absorption of a cyano group in the extensively conjugated compound. It owns odd photophysical characteristics connected with the arrangement of amino and cyano groups in the diene ring. The compound is built up by consecutive one-pot reaction of two molecules of malononitrile carbanion and a ketonic substrate, and the reaction mechanism continues by a new type of tandem carbon-carbon cyclization that comprises a final elimination of cyanate ion.Reaction of 2-chloroisobutyrophenone with two equivalents of malononitrile anion furnishes 2-amino-1,3-dicyano-5,5-dimethyl-4-phenylcyclopenta-1,3-diene. The cyclic compound represents the novel 2-amino-1,3-dicyanocyclopentadiene structure. The unique 1-cyano-2-amino-3-cyano arrangement in a cyclopentadienic ring brings about a strong polarization of the electronic configuration of the diene pi system that is conformed by two opposite dipolar halves as revealed by IR and 13C NMR data for the compound. Such polarized configuration accounts for the extreme persistence manifested by the compound in contrast with unsubstituted cyclopentadiene. The cyclopentadiene owns a vivid lemon-hued yellow color consequent to an unusually intense n pi absorption of a cyano group in the extensively conjugated compound. It owns odd photophysical characteristics connected with the arrangement of amino and cyano groups in the diene ring. The compound is built up by consecutive one-pot reaction of two molecules of malononitrile carbanion and a ketonic substrate, and the reaction mechanism continues by a new type of tandem carbon-carbon cyclization that comprises a final elimination of cyanate ion. 52 pp. Englisch. N° de réf. du vendeur 9786203923827
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Branched 2-amino-1, 3-dicyanocyclopenta-1, 3-diene : Synthesis and structural properties
Edité par
LAP LAMBERT Academic Publishing, 2021
ISBN 10 : 6203923826
ISBN 13 : 9786203923827
Neuf
Taschenbuch
Vendeur : AHA-BUCH GmbH, Einbeck, Allemagne
Évaluation du vendeur 5 sur 5 étoiles
Taschenbuch. Etat : Neu. nach der Bestellung gedruckt Neuware - Printed after ordering - Reaction of 2-chloroisobutyrophenone with two equivalents of malononitrile anion furnishes 2-amino-1,3-dicyano-5,5-dimethyl-4-phenylcyclopenta-1,3-diene. The cyclic compound represents the novel 2-amino-1,3-dicyanocyclopentadiene structure. The unique 1-cyano-2-amino-3-cyano arrangement in a cyclopentadienic ring brings about a strong polarization of the electronic configuration of the diene pi system that is conformed by two opposite dipolar halves as revealed by IR and 13C NMR data for the compound. Such polarized configuration accounts for the extreme persistence manifested by the compound in contrast with unsubstituted cyclopentadiene. The cyclopentadiene owns a vivid lemon-hued yellow color consequent to an unusually intense n pi absorption of a cyano group in the extensively conjugated compound. It owns odd photophysical characteristics connected with the arrangement of amino and cyano groups in the diene ring. The compound is built up by consecutive one-pot reaction of two molecules of malononitrile carbanion and a ketonic substrate, and the reaction mechanism continues by a new type of tandem carbon-carbon cyclization that comprises a final elimination of cyanate ion.Reaction of 2-chloroisobutyrophenone with two equivalents of malononitrile anion furnishes 2-amino-1,3-dicyano-5,5-dimethyl-4-phenylcyclopenta-1,3-diene. The cyclic compound represents the novel 2-amino-1,3-dicyanocyclopentadiene structure. The unique 1-cyano-2-amino-3-cyano arrangement in a cyclopentadienic ring brings about a strong polarization of the electronic configuration of the diene pi system that is conformed by two opposite dipolar halves as revealed by IR and 13C NMR data for the compound. Such polarized configuration accounts for the extreme persistence manifested by the compound in contrast with unsubstituted cyclopentadiene. The cyclopentadiene owns a vivid lemon-hued yellow color consequent to an unusually intense n pi absorption of a cyano group in the extensively conjugated compound. It owns odd photophysical characteristics connected with the arrangement of amino and cyano groups in the diene ring. The compound is built up by consecutive one-pot reaction of two molecules of malononitrile carbanion and a ketonic substrate, and the reaction mechanism continues by a new type of tandem carbon-carbon cyclization that comprises a final elimination of cyanate ion. N° de réf. du vendeur 9786203923827
Quantité disponible : 1 disponible(s)
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Branched 2-amino-1, 3-dicyanocyclopenta-1, 3-diene
Edité par
LAP LAMBERT Academic Publishing Jun 2021, 2021
ISBN 10 : 6203923826
ISBN 13 : 9786203923827
Neuf
Taschenbuch
Vendeur : buchversandmimpf2000, Emtmannsberg, BAYE, Allemagne
Évaluation du vendeur 5 sur 5 étoiles
Taschenbuch. Etat : Neu. Neuware -Reaction of 2-chloroisobutyrophenone with two equivalents of malononitrile anion furnishes 2-amino-1,3-dicyano-5,5-dimethyl-4-phenylcyclopenta-1,3-diene. The cyclic compound represents the novel 2-amino-1,3-dicyanocyclopentadiene structure. The unique 1-cyano-2-amino-3-cyano arrangement in a cyclopentadienic ring brings about a strong polarization of the electronic configuration of the diene ¿ system that is conformed by two opposite dipolar halves as revealed by IR and 13C NMR data for the compound. Such polarized configuration accounts for the extreme persistence manifested by the compound in contrast with unsubstituted cyclopentadiene. The cyclopentadiene owns a vivid lemon-hued yellow color consequent to an unusually intense n ¿ ¿¿ absorption of a cyano group in the extensively conjugated compound. It owns odd photophysical characteristics connected with the arrangement of amino and cyano groups in the diene ring. The compound is built up by consecutive one-pot reaction of two molecules of malononitrile carbanion and a ketonic substrate, and the reaction mechanism continues by a new type of tandem carbon-carbon cyclization that comprises a final elimination of cyanate ion.Books on Demand GmbH, Überseering 33, 22297 Hamburg 52 pp. Englisch. N° de réf. du vendeur 9786203923827
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Branched 2-amino-1, 3-dicyanocyclopenta-1, 3-diene: Synthesis and structural properties
Edité par
LAP LAMBERT Academic Publishing, 2021
ISBN 10 : 6203923826
ISBN 13 : 9786203923827
Neuf
paperback
Vendeur : Mispah books, Redhill, SURRE, Royaume-Uni
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paperback. Etat : New. New. book. N° de réf. du vendeur ERICA80062039238266
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