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Synopsis
《研究生规划教材：烯烃配位聚合理论与实践（第2版）》以ZieglerNatta催化剂的发现、发展和演进为主线，全面系统地论述了α烯烃、二烯烃和环烯烃的配位聚合理论和聚合方法的发展和现状。《研究生规划教材：烯烃配位聚合理论与实践（第2版）》共分6章，在第1章概论中，首先对烯烃配位聚合的性质和特点进行梗概描述，随后介绍了该领域中常用术语和概念的物理含义及其与配位聚合术语的相关性。还从物理化学的角度详细地讨论了研究和生产中常用术语，如催化活性、催化效率、萃取分离、结晶和立构规整度等的物理含义和表征方法，以期对深入理解配位聚合本质和正确使用表征方法奠定科学基础。第2章是烯烃配位聚合催化剂，在该章中详细地论述了各类催化剂的发现、发展和演进过程。对重要的催化剂体系如ZieglerNatta催化剂、茂金属催化剂和后过渡金属催化剂，一是客观地介绍了它们的发现、发展、演进过程和发展标志；二是依据催化剂各组分间的反应推演出各类催化剂高（活性）（长）效化的思路和方法，以及由这些催化剂合成的聚烯烃结构和物性特征。第3、4、5、6章分别是α烯烃配位均聚、α烯烃烯烃配位共聚、二烯烃和环烯烃的配位聚合。各章中有关烯烃配位聚合理论的建立和发展的论述，是以催化剂的进步为脉络，较系统地讨论了各种理论的主要观点、实验证据、分子描述及其演进过程，并分析了它们的合理性和预见性。还对各类催化剂的结构异同点、聚合机理的完善程度和争论焦点进行了类比评述。为了便于读者查证和深究，对重要的催化剂、制备方法和理论观点还引用了相应的参考文献，供有兴趣的读者进一步查询和参考。《研究生规划教材：烯烃配位聚合理论与实践（第2版）》可作为高分子合成、高分子材料专业本科生、研究生的教学参考资料，也可供从事烯烃聚合和材料加工的科研人员、企业开发和信息研究人员等参考。第1章概论1.1烯烃配位聚合的性质和特点1.2适于配位聚合的单体和催化剂1.2.1单体类型和聚合物结构1.2.2催化剂类型1.3α烯烃配位聚合实施方法1.3.1溶液聚合1.3.2淤浆聚合1.3.3本体聚合1.4与配位聚合相关的术语和概念1.4.1各种聚合术语的含意及其与配位聚合的相关性1.4.2与配位聚合相关的物化概念参考文献第2章ZieglerNatta催化剂及其演进2.1ZieglerNatta催化剂的发现和性质2.1.1Ziegler催化剂和Natta催化剂的发现2.1.2Ziegler和Natta催化剂的性质2.1.3ZieglerNatta催化剂的组分和性质2.2ZieglerNatta催化剂的演进2.2.1研磨法2.2.2负载法2.3茂金属催化剂2.3.1茂金属催化剂的命名和组成2.3.2茂金属催化剂的发现和特性2.3.3茂金属催化剂研发进展2.3.4工业专用茂金属催化剂举例2.3.5茂金属催化剂解析和评价2.4后过渡金属催化剂2.4.1后过渡金属催化剂的发现2.4.2后过渡金属催化剂组成及其催化α烯烃聚合特征2.4.3后过渡金属催化剂发展参考文献第3章α烯烃的配位聚合3.1乙烯的配位聚合3.1.1聚乙烯的类型和特性3.1.2乙烯配位聚合催化剂和聚合方法3.1.3配位聚合机理和聚合动力学3.2丙烯的立构规整聚合
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Graduate planning materials: olefin coordination polymerization Theory and Practice (2nd edition)(Chinese Edition)
ISBN 10 : 7122129438
ISBN 13 : 9787122129437
Neuf
paperback
Vendeur : liu xing, Nanjing, JS, Chine
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paperback. Etat : New. Ship out in 2 business day, And Fast shipping, Free Tracking number will be provided after the shipment.Paperback. Pub Date: 2013 Pages: 331 Publisher: Chemical Industry Press graduate planning materials: olefin coordination polymerization Theory and Practice (2nd Edition) main line to the discovery. development and evolution of the Ziegler Natta catalysts. comprehensive systematically discusses the development and current status of the theory and method of polymerization of alpha olefins. diolefins and cyclic olefin coordination polymerization. The graduate planning materials: olefin coordination polymerization Theory and Practice (2nd edition) is divided into six chapters. Chapter 1 Introduction. outline description of the nature and characteristics of the first olefin coordination polymerization. followed by the field common terms and the physical meaning of the concept and its correlation with the coordination polymerization terminology. From the physical and chemical point of view in detail the research and production of commonly used terminology such as catalytic activity. the catalytic efficiency of extraction. separation crystalline and stereoregular regular degrees such as the physical meaning and characterization methods. to phase in-depth understanding of coordination polymerization essence and proper use of characterization methods to establish the scientific basis. Chapter 2 olefin coordination polymerization catalyst. and the discovery. development. and the evolution of the various types of catalysts are discussed in detail in this chapter. Important catalyst systems such as Ziegler Natta catalysts. metallocene catalysts and late transition metal catalysts. one objective presentation of their discovery. development. evolution and development of flag; second is based on the reaction between the various components of the catalyst to deduce class of catalyst (active) (L) efficiency of the ideas and methods. as well as the synthesis of these catalysts polyolefin structure and physical properties characteristics. 3.4.5.6 ligand of the -olefin homopolymerization. copolymerization of alpha-olefin olefins ligand coordination polymerization of diolefins and cyclic olefins. Olefin coordination polymerization on the establishment and development of the theory in each chapter discusses. in the progress of the catalyst as a context. a more systematic discussion of the main points of the various theories. experimental evidence. molecular description of its evolutionary process. and analyze their rationality and predictability. Structural similarities and differences between the various types of catalysts. polymerization degree of perfection of the mechanism and the focus of debate the analogy commentary. In order to facilitate the reader to verify and get to the bottom of the important catalyst preparation method and theoretical perspectives references corresponding references for interested readers further inquiries and reference. The graduate planning materials: olefin coordination polymerization Theory and Practice (2nd edition) can be used as polymer synthesis. polymer materials undergraduate. graduate teaching reference materials are also available for researchers engaged olefin polymerization and materials processing enterprise development and information researchers Reference. Contents: Chapter 1 Introduction 1.1 olefin coordination polymerization of the nature and characteristics of the 1.2 suitable for coordination polymerization. monomer and catalyst 1.2.1 monomer type and polymer structure 1.2.2 catalyst type 1.3 olefin the coordination polymerization implementation method 1.3 1.4.2 slurry polymerization .1 solution polymerization 1.3.2 1.3.3 bulk polymerization of 1.4 with the the coordination polymerization term and concept 1.4.1 various polymerization term implications of their coordination polymerization and coordination polymerization discovery and the nature of the the concept materialized References Chapter 2. N° de réf. du vendeur NE023286
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