An Ordering Concept on the Basis of Alternative Principles in Chemistry : Design of Chemicals and Chemical Reactions by Differentiation and Compensation

Paul Heimbach

ISBN 10: 3642838081 / ISBN 13: 9783642838088

Edité par Springer Berlin Heidelberg, 2011

A propos de cet article

Druck auf Anfrage Neuware - Printed after ordering - Considering aspects of symmetry rules in chemistry, one is faced with con tradictory terms as for example, '90 % concertedness' sometimes being used in literature. To accept conservation of orbital symmetry to be as controlled as inversion by alternative principles seems far more promising. The intention of this book is aimed at introducing a qualitative understanding of phase rela tions in electromagnetic interactions. Avoiding one-sided dogmatism we tried to demonstrate the importance of alternative principles as guidelines to the evolution of alternative order in chemical systems. Passing through the jungle of information it became extremly important to control again and again our insights into the ordering phenomena by experi ments under conditions as coherent as possible. We became more aware of the fact that chemistry - the science of 'becoming' in complex systems - can not be understood by mechanistic details, i. e. THROUGHPUT-studies alone, because the mechanism is only true for the special system under inves tigation and does not offer a tool for the evolution of opposite order. We had to accept chemistry as a mediator between molecular physics and general epistemology. This quite unusual combination was directed by excel lent teachers and the realizations were made possible by enthusiastic, open minded coworkers (see references). The next target we will strive for on this journey will be to quantify the alternative principles, that means obtaining the order parameters of H. Haken (e. g. in asymmetric synthesis).

N° de réf. du vendeur 9783642838088

Détails bibliographiques

• Titre: An Ordering Concept on the Basis of Alternative Principles in Chemistry : Design of Chemicals and Chemical Reactions by Differentiation and Compensation
• Éditeur: Springer Berlin Heidelberg
• Date de parution: 2011
• Langue: anglais
• ISBN à 10 chiffres: 3642838081
• ISBN à 13 chiffres: 9783642838088
• Reliure: Taschenbuch
• État de l'article: Neu
• Dimensions: 242 L x 170 H x 13 P (en millimètres) 242 millimètres de largeur par 170 millimètres de hauteur par 13 millimètres de profondeur
• Poids: 412 grammes

A propos de ce titre

Synopsis

Considering aspects of symmetry rules in chemistry, one is faced with con- tradictory terms as for example, "90 % concertedness" sometimes being used in literature. To accept conservation of orbital symmetry to be as controlled as inversion by alternative principles seems far more promising. The intention of this book is aimed at introducing a qualitative understanding of phase rela- tions in electromagnetic interactions. Avoiding one-sided dogmatism we tried to demonstrate the importance of alternative principles as guidelines to the evolution of alternative order in chemical systems. Passing through the jungle of information it became extremly important to control again and again our insights into the ordering phenomena by experi- ments under conditions as coherent as possible. We became more aware of the fact that chemistry - the science of "becoming" in complex systems - can not be understood by mechanistic details, i. e. THROUGHPUT-studies alone, because the mechanism is only true for the special system under inves- tigation and does not offer a tool for the evolution of opposite order. We had to accept chemistry as a mediator between molecular physics and general epistemology. This quite unusual combination was directed by excel- lent teachers and the realizations were made possible by enthusiastic, open- minded coworkers (see references). The next target we will strive for on this journey will be to quantify the alternative principles, that means obtaining the order parameters of H. Haken (e. g. in asymmetric synthesis).

Présentation de l'éditeur

The authors intend to make synthetic chemists aware of an alternative approach towards developing improved experimental strategies. Alternative "order factors" are used to describe the evolution of alternative order in complex chemical systems. The general concept is derived from the authors' own experimental experience and from published material.