Hardcover. A unique guide to variable temperature CD spectroscopy and its application in organic chemistry This timely, original, thought-provoking work looks at organic stereochemistry from the perspective of circular dichroism (CD), using variable temperature CD spectroscopy to determine the conformation or absolute configuration of chiral molecules. With an emphasis on the analysis of optically active ketones and the carbonyl chromophore, the authors demonstrate the advantages of this highly sensitive spectroscopic tool for obtaining stereochemical information in diverse areas of organic chemistry, biochemistry, and medicinal/pharmaceutical chemistry. They combine detailed examples of stereochemical analysis with clear, thorough presentations, correlating chiroptical data with molecular mechanics calculations as well as data from NMR spectroscopy and other spectroscopic techniques. In addition, they provide a systematic survey of the professional literature, featuring an extraordinary collection of original CD spectra run at varying temperatures. Coverage includes: * Chiroptical measurements: CD and ORD (Optical Rotatory Dispersion) * Conformational analysis of compounds ranging from simple cyclic ketones to polycyclics * Conjugated and homoconjugated systems * Stereochemistry of the carbon-carbon double bond * Stereochemistry from exciton coupling of two or more chromophores * An interesting historical account of the development of stereochemical concepts A unique guide to variable temperature CD spectroscopy and its application in organic chemistry This timely, original, thought-provoking work looks at organic stereochemistry from the perspective of circular dichroism (CD), using variable temperature CD spectroscopy to determine the conformation or absolute configuration of chiral molecules. Shipping may be from multiple locations in the US or from the UK, depending on stock availability.

N� de r�f. du vendeur 9780471354055

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D�tails bibliographiques

Titre: Organic Conformational Analysis and Stereochemistry from Circular Dichroism Spectroscopy (Hardcover)
�diteur: John Wiley & Sons Inc, Berlin
Date de parution: 2000
Langue: anglais
ISBN � 10 chiffres: 0471354058
ISBN � 13 chiffres: 9780471354055
Reliure: Hardcover
�dition: Edition originale
�tat de l'article: new

A propos de ce titre

Synopsis

Unter Zirkulardichroismus (CD) versteht man die spezifisch unterschiedliche Absorption von links- und rechtszirkular polarisiertem Licht durch bestimmte Molek�le. CD-Effekte lassen sich in Abh�ngigkeit von der Wellenl�nge messen und spektroskopisch auswerten; sie geben beispielsweise Auskunft �ber die Konformation organischer Verbindungen. Dieses Buch richtet sich an den organischen Chemiker, der mit den Grundprinzipien der Stereochemie vertraut ist, und erl�utert die Anwendung der CD-Spektroskopie zur Konformationsanalyse ausf�hrlich und verst�ndlich. (06/00)

� propos de l?auteur

DAVID A. LIGHTNER, PhD, is R. C. Fuson Professor of Chemistry at the University of Nevada, Reno.
JEROME E. GURST, PhD, is Professor of Chemistry at the University of West Florida, Pensacola.

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