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Etat : New. Gennady Zaikov, Yuri Monakov, Natalia Sigaeva, Vadim UrazbaevThe monograph is intended to systematize data on active sites and their kinetic and stereospecific heterogeneity (polysite phenomenon) in olefin and diene monomer ion, ion-coordination and com.

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Buch. Etat : Neu. Neuware - The monograph is intended to systematize data on active sites and their kinetic and stereospecific heterogeneity (polysite phenomenon) in olefin and diene monomer ion, ion-coordination and complex radical polymerization processes. Questions of molecular-mass distribution of polymers obtained by ion and ion-coordination polymerization methods are discussed together with composition and stereo regularity distribution of olefin copolymers. Data on the influence of transition and non-transition metal origin and their ligand ambience, conditions of catalytic system preparation and polymerization are shown. Various assessment methods of polymerization active site distribution by kinetic activity and stereospecific action are considered. In particular, an assessment method for kinetic activity distribution at ion-coordination diene polymerization is described, mathematical simulation parameters for polymerization processes are shown, taking into account the polysite structure of catalytic systems.Of special attention are geometrical and electron structure of active sites in the ion-coordination polymerization by the quantum chemistry method, interrelation between reactivity of some types of active sites and stereospecificity of their action in diene polymerization. The importance of ratio between specific time elementary act duration at the diene injection, coordinated on an active site, and time of propagating macrochain end unit existence in the s-state at polydiene microstructure formation is indicated. Questions of the polysite mechanism occurrence in complex radical polymerization processes are discussed. A possibility for polymerization to proceed in both free-radical and complex related chain propagation sites is shown.…

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HRD. Etat : New. New Book. Shipped from UK. Established seller since 2000.

HRD. Etat : New. New Book. Shipped from UK. Established seller since 2000.

Hardcover. Etat : new. Hardcover. The monograph is intended to systematize data on active sites and their kinetic and stereospecific heterogeneity (polysite phenomenon) in olefin and diene monomer ion, ion-coordination and complex radical polymerization processes. Questions of molecular-mass distribution of polymers obtained by ion and ion-coordination polymerization methods are discussed together with composition and stereo regularity distribution of olefin copolymers. Data on the influence of transition and non-transition metal origin and their ligand ambience, conditions of catalytic system preparation and polymerization are shown. Various assessment methods of polymerization active site distribution by kinetic activity and stereospecific action are considered. In particular, an assessment method for kinetic activity distribution at ion-coordination diene polymerization is described, mathematical simulation parameters for polymerization processes are shown, taking into account the polysite structure of catalytic systems. Of special attention are geometrical and electron structure of active sites in the ion-coordination polymerization by the quantum chemistry method, interrelation between reactivity of some types of active sites and stereospecificity of their action in diene polymerization. The importance of ratio between specific time elementary act duration at the diene injection, coordinated on an active site, and time of propagating macrochain end unit existence in the s-state at polydiene microstructure formation is indicated. Questions of the polysite mechanism occurrence in complex radical polymerization processes are discussed. A possibility for polymerization to proceed in both free-radical and complex related chain propagation sites is shown. Data on polysite phenomenon (distribution of active sites by kinetic activity and stereospecificity of action) in polymerization are analyzed. The examples of polysite phenomenon manifestation and assessment, and its connection with ion, ion-coordination and radical polymerization conditions for olefins and dienes are shown. Geometrical and electron structure of active sites in ion-coordination polymerization of dienes is considered and the relation between the structure, reactivity and stereospecificity of action of different site types is shown. Shipping may be from multiple locations in the US or from the UK, depending on stock availability.…

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Etat : As New. Unread book in perfect condition.

Hardcover. Etat : new. Hardcover. The monograph is intended to systematize data on active sites and their kinetic and stereospecific heterogeneity (polysite phenomenon) in olefin and diene monomer ion, ion-coordination and complex radical polymerization processes. Questions of molecular-mass distribution of polymers obtained by ion and ion-coordination polymerization methods are discussed together with composition and stereo regularity distribution of olefin copolymers. Data on the influence of transition and non-transition metal origin and their ligand ambience, conditions of catalytic system preparation and polymerization are shown. Various assessment methods of polymerization active site distribution by kinetic activity and stereospecific action are considered. In particular, an assessment method for kinetic activity distribution at ion-coordination diene polymerization is described, mathematical simulation parameters for polymerization processes are shown, taking into account the polysite structure of catalytic systems. Of special attention are geometrical and electron structure of active sites in the ion-coordination polymerization by the quantum chemistry method, interrelation between reactivity of some types of active sites and stereospecificity of their action in diene polymerization. The importance of ratio between specific time elementary act duration at the diene injection, coordinated on an active site, and time of propagating macrochain end unit existence in the s-state at polydiene microstructure formation is indicated. Questions of the polysite mechanism occurrence in complex radical polymerization processes are discussed. A possibility for polymerization to proceed in both free-radical and complex related chain propagation sites is shown. Data on polysite phenomenon (distribution of active sites by kinetic activity and stereospecificity of action) in polymerization are analyzed. The examples of polysite phenomenon manifestation and assessment, and its connection with ion, ion-coordination and radical polymerization conditions for olefins and dienes are shown. Geometrical and electron structure of active sites in ion-coordination polymerization of dienes is considered and the relation between the structure, reactivity and stereospecificity of action of different site types is shown. Shipping may be from our Sydney, NSW warehouse or from our UK or US warehouse, depending on stock availability.…

Hardcover. Etat : Brand New. 397 pages. 9.50x6.25x1.00 inches. In Stock.

Etat : New. pp. ix + 397 Illus. This item is printed on demand.

Taschenbuch. Etat : Neu. nach der Bestellung gedruckt Neuware - Printed after ordering - Please note that the content of this book primarily consists of articles available from Wikipedia or other free sources online. Sandymount is the name of a prominent hill on Otago Peninsula, in the southeastern South Island of New Zealand. It is 13 kilometres east of the city centre of Dunedin, close to the northeastern end of Sandfly Bay, and rises to a height of 312 metres. The eastern side of the hill meets the Pacific Ocean in a series of high cliffs and chasms, some of which are among the largest in New Zealand. Prominent among these are Lover's Leap and The Chasm, the former of which is 224 metres high. The hill is named for the large dunes which rise up the southern flanks of the hill to a height of over 100 metres.…