Elsevier bv sep 2002 (4 résultats)

Taschenbuch. Etat : Neu. Neuware - In control and signal processing, adaptation is a natural tool to cope with real-time changes in the dynamical behaviour of signals and systems. In this area, strongly connected with prediction and identification, there has been an increasing interest in switching and supervising methods. Moreover in recent years, special attention has been paid to the ideas evolving round the theory of statistical learning as a potential tool of improved adaptation.The IFAC workshop on Adaptation and Learning in Control and Signal Processing in 2001 gathered together experts in the field and interested researchers from universities and industry to present a full picture of the area. This proceedings volume presents papers covering the following subjects: Model reference and predictive control; Multiple model control; Adaptive control I/II; Adaptive control and learning; Learning; Adaptive control of nonlinear systems I/II; Supervisory control; Neural networks for control; PID design methods; Sliding mode; Adaptive filtering and estimation; Identification methods I/II.…

Buch. Etat : Neu. Neuware - Gold (H. Schmidbaur). Copper and Silver (G. van Koten). Mercury (J.L. Wardell). Cadmium and Zinc (P. O'Brien).

Buch. Etat : Neu. Neuware - In recent decades, magnetism has seen an enormous expansion into a variety of different areas of research, including the magnetism of several classes of novel materials that share only the presence of magnetic moments with truly ferromagnetic materials.

Buch. Etat : Neu. Neuware - Clathrochelates are compounds which contain a metal ion encapsulated within a three dimensional cage of macrobicyclic ligand atoms. Within this cage the metal has unique properties and is to a great extent isolated from environmental factors. Such complexes are suitable as models of the most essential biological systems, membrane transport, electron carriers, highly selective and sensitive analytical reagents, catalysts for photochemical and redox processes, cation and anion receptors, etc. The aim of this monograph is to generalize and analyze experimental and theoretical data on clathrochelates in order to promote further research in this promising field of chemistry.Chapter 1 gives general concepts of complexes with encapsulated metal ions, discusses basic specific features of these compounds, considers and characterizes the main types of compounds with encapsulated metal ions and the main classes of clathrochelates, and includes the current nomenclature. Chapter 2 deals with the pathways of clathrochelate synthesis and the general procedures for the synthesis of macrobicyclic tris-dioximates, phosphorus-containing tris-diiminates, sepulchrates, sarcophagi-nates, and polyene and other types of clathrochelate complexes. Chapter 3 concerns studies of the electronic and spatial structure of clathrochelate complexes. In Chapter 4, the kinetics and mechanism of synthesis and decomposition reactions of macrobicyclic tris-dioximates, sarcophaginates, and sepulchrates in solution and gas phases are discussed. Chapter 5 considers the electrochemical, photochemical, and some other characteristics of clathrochelates and their applications associated with these characteristics. Finally, the practical applications of the unique properties of clathrochelates and perspectives on the synthesis of new clathrochelates are described in Chapters 6 and 7, respectively.…